Role of zero-point effects in catalytic reactions involving hydrogen

According to the Heisenberg uncertainty principle of quantum mechanics, particles which are localized in space by a bounding potential must have a finite distribution of momenta. This leads, even in the lowest possible energy state, to vibrations, and thus, to the so-called zero-point energy. For chemically bound hydrogen the zero-point energy can be quite substantial. For example, for a free H2 molecule it is 0.26 eV, a significant value in the realm of chemistry, where often an energy of the order of 0.1 eV/atom (or 2.3 kcal/mol) decides whether or not a chemical reaction takes place with an appreciable rate. Yet, in many theoretical studies the dynamics of chemical reactions involving hydrogen has been treated classically or quasiclassically, assuming that the quantum mechanical nature of H nuclei, i.e., the zero-point effects, will not strongly affect the relevant physical or chemical properties. In this article we show that this assumption is not justified. We will demonstrate that for very basic and...