Damped soft phonons and diffuse scattering in 40%Pb(Mg1∕3Nb2∕3)O3-60%PbTiO3
/ Authors
C. Stock, D. Ellis, I. Swainson, Guangyong Xu, H. Hiraka, Z. Zhong, Hong-Bing Luo, X. Zhao, Dwight Viehland, R. Birgeneau
and 2 more authors
/ Abstract
(PT). We measure the structural properties of PMN-60PT to be identical topure PT, however, the lattice dynamics are exactly that previously found in relaxors PMN and PZN.PMN-60PT displays a well-defined macroscopic structural transition from a cubic to tetragonal unitcell at 550 K. The diffuse scattering is shown to be weak indicating that the structural distortionis long-range in PMN-60PT and short-range polar correlations (polar nanoregions) are not present.Even though polar nanoregions are absent, the soft optic mode is short-lived for wavevectors near thezone-centre. Therefore, PMN-60PT displays the same waterfall effect as prototypical relaxors PMNand PZN. We conclude that it is random fields resulting from the intrinsic chemical disorder whichis the reason for the broad transverse optic mode observed in PMN and PMN-60PT near the zonecentre and not due to the formation of short-ranged polar correlations. Through our comparisonof PMN, PMN-60PT, and pure PT, we interpret the dynamic and static properties of the PMN-xPT system in terms of a random field model in which the cubic anisotropy term dominates withincreasing doping of PbTiO
Journal: Physical Review B