Soft-x-ray spectroscopy measurements of the p-like density of states of B in MgB 2 and evidence for surface boron oxides on exposed surfaces
/ Authors
T. A. Callcott, L. Lin, G. T. Woods, G. P. Zhang, J. Thompson, M. Paranthaman, D. L. S. U. O. Tennessee, Knoxville, Tn, Oak Ridge National Laboratory
and 4 more authors
/ Abstract
Soft-x-ray absorption and fluorescence measurements are reported for the K edge of B in MgB{sub 2}. The measurements confirm a high density of B p{sub xy}({sigma}) states at the Fermi edge and extending to approximately 0.9 eV above the edge. A strong resonance is observed in elastic scattering through a core exciton derived from out-of-plane p{sub z}({pi}{sup *}) states. Another strong resonance, observed in both elastic and inelastic spectra, is identified as a product of surface boron oxides.
Journal: Physical Review B