Valley polarization of chiral excitonic bound states induced by band geometry

Van der Waals (vdW) materials provide a rich platform for exploring the interplay of interactions, topology, and paired-electron phases. We study how the Berry phase reshapes excitonic pairing in a double-well dispersion representative of layered vdW systems. By computing the temperature-versus-Berry flux phase diagram of the system, we find parameter ranges where finite angular momentum excitons are favored, including chiral states. Strikingly, the condensed angular momentum channel evolves with Berry flux, revealing a pairing problem with no analogue in a hydrogen atom in a uniform magnetic field, where angular momentum states never cross. We then turn to a model of multilayer rhombohedral graphene and examine the effects of trigonal warping. Once continuous rotational symmetry is broken, excitons mix multiple angular momenta, and for a range of parameters we find a variety of linear combination of angular momenta ($s, p, f$ and $g$) in the ground state. Our results point to the possibility of chiral excitonic condensates, and spontaneous symmetry breaking through many-body condensation.