/ AbstractThe sub-millimetre dust opacity spectral index is a critical observable to constrain dust properties, such as the maximum grain size of an observed dust population. It has been widely measured at galactic scales and down to protoplanetary disks. However, because of observational and analytical challenges, quite a gap exists in measuring dust properties in the envelopes that feed newborn protostars and their disks. To fill this gap, we use sensitive dust continuum emission data at 1.2 and 3.1 mm from the ALMA FAUST Large Program and constrain the dust opacity millimetre spectral index around a sample of protostars. Our high-resolution data, along with a more refined methodology with respect to past efforts, allow us to disentangle disk and envelope contributions in the uv-plane, and thus measure spectral indices for the envelopes uncontaminated by the optically thick emission of the inner regions. First, we find that the young disks are small and optically thick. Secondly, we measure the dust opacity spectral index at envelope scales for n=11 sources: the beta of n=9 sources had never been constrained in the literature. We effectively double the number of sources for which the dust opacity spectral index beta has been measured at these scales. Third, combining the available literature measurements with our own (total n=18), we show how envelope spectral indices distribute between ISM-like and disk-like values, bridging the gap in the inferred dust evolution. Finally, we statistically confirm a significant correlation between beta and the mass of protostellar envelopes, previously suggested in the literature. Our findings indicate that the dust optical properties smoothly vary from the ISM, through envelopes and all the way down to disks. Multi-wavelength surveys are needed to further this study and make more general claims on dust evolution in its pathway from cloud to disks.