Symmetry Breaking in the Superionic Phase of Silver Iodide.

In the superionic phase of silver iodide, we observe a distorted tetragonal structure characterized by symmetry breaking in the cation distribution. This phase competes with the well known bcc phase with a symmetric cation distribution, at an energetic cost of only a few meV/atom. The small energy difference suggests that these competing structures may both be thermally accessible near the superionic transition temperature. We also find that the distribution of silver ions depends on the low-temperature parent polymorph, with memory persisting in the superionic phase on the nanosecond timescales accessible in our simulations. Furthermore, simulations on the order of 100 ns reveal that even at temperatures where the bcc phase is stable, significant fluctuations toward the tetragonal lattice structure remain. Our results are consistent with many "anomalous" experimental observations and offer a molecular mechanism for the "memory effect" in silver iodide.