Nanoscale dynamics of hydrogen in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>VO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math> studied by <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mi>μ</mml:mi><mml:mi>SR</mml:mi></mml:mrow></mml:math
/ Authors
/ Abstract
Hydrogen dynamics in the nanoscale region of VO$_{2}$ was investigated by muon spin rotation/relaxation ($\mu $SR) technique. Positively charged muon acts as a light radioisotope of proton and can be used as a probe to explore the inside of materials from an atomic perspective. By analyzing the muon hopping rate and the spatial distribution of the $^{51}$V nuclear magnetic moments, we have identified two types of diffusion paths in VO$_{2}$ (via oxygen-muon bonds or defects) and the potential of a high diffusion coefficient in the 10$^{-10}$ cm$^{2}$/s range at ambient temperature. Our results provide valuable information for developing hydrogen-driven VO$_{2}$--related electronic devices.
Journal: Physical Review Materials