Interfacial stress transfer in monolayer and few-layer MoS2 nanosheets in model nanocomposites
/ Authors
/ Abstract
Understanding the stress transfer mechanisms from a polymer matrix to two-dimensional (2D) reinforcements is essential for the preparation of high performance nanocomposites. In this study, the interfacial stress transfer from a flexible polymer substrate to monolayer and few-layer molybdenum disulfide (MoS 2 ) under tension has been investigated. Layer-dependent and strain-dependent photoluminescence (PL) spectroscopy were used to examine the stress transfer efficiency. The interlayer stress transfer efficiency of MoS 2 was determined to be in the range of 0.76 – 0.86, higher than that of graphene. The transfer of strain from the polymer substrate to the flakes was derived through strain-dependent band shifts. With progressive loading, the strain distribution in monolayer MoS 2 can be described by the shear-lag, partial-debonding and total-debonding models. The interfacial shear and frictional stresses were calculated to quantify the strength of the MoS 2 /polymer interface. It was found that the strength of the interface is similar to the strength of a graphene-polymer interface. Strain mapping was performed at different strain levels and it was found that the strain distribution in bilayer MoS 2 is similar to the case of a monolayer sample. The interfacial shear strength remains almost unaffected, while the stress transfer length increases with increasing layer number.
Journal: Composites Science and Technology