/ AbstractWe report the triton ($t$) production in mid-rapidity ($|y| <$ 0.5) Au+Au collisions at $\sqrt{s_\mathrm{NN}}$= 7.7--200 GeV measured by the STAR experiment from the first phase of the beam energy scan at the Relativistic Heavy Ion Collider (RHIC). The nuclear compound yield ratio ($\mathrm{N}_t \times \mathrm{N}_p/\mathrm{N}_d^2$), which is predicted to be sensitive to the fluctuation of local neutron density, is observed to decrease monotonically with increasing charged-particle multiplicity ($dN_{ch}/dη$) and follows a scaling behavior. The $dN_{ch}/dη$ dependence of the yield ratio is compared to calculations from coalescence and thermal models. Enhancements in the yield ratios relative to the coalescence baseline are observed in the 0\%-10\% most central collisions at 19.6 and 27 GeV, with a significance of 2.3$σ$ and 3.4$σ$, respectively, giving a combined significance of 4.1$σ$. The enhancements are not observed in peripheral collisions or model calculations without critical fluctuation, and decreases with a smaller $p_{T}$ acceptance. The physics implications of these results on the QCD phase structure and the production mechanism of light nuclei in heavy-ion collisions are discussed.