Hybrid exciton-plasmon-polaritons in van der Waals semiconductor gratings

Van der Waals materials and heterostructures that manifest strongly bound exciton states at room temperature also exhibit emergent physical phenomena and are of great promise for optoelectronic applications. Here, we demonstrate that nanostructured, multilayer transition metal dichalcogenides (TMDCs) by themselves provide an ideal platform for excitation and control of excitonic modes, paving the way to exciton-photonics. Hence, we show that by patterning the TMDCs into nanoresonators, strong dispersion and avoided crossing of exciton, cavity photons and plasmon polaritons with effective separation energy exceeding 410 meV can be controlled with great precision. We further observe that inherently strong TMDC exciton absorption resonances may be completely suppressed due to excitation of hybrid light-matter states and their interference. Our work paves the way to the next generation of integrated exciton optoelectronic nano-devices and applications in light generation, computing, and sensing. The authors investigate the optical properties of a heterostructure formed by a metallic substrate and a nanostructured transition metal dichalcogenide multilayer by measuring the reflectance spectrum at different multilayer thicknesses, filling factors and grating periods. The spectra show strong dispersion and avoided crossing of excitons, plasmons and cavity photons along with excitonic mode suppression at the anti-crossing point.