Ultracold homonuclear and heteronuclear collisions in metastable helium

Scattering and ionizing cross sections and rates are calculated for ultracold collisions between metastable helium atoms using a fully quantum-mechanical close-coupled formalism. Homonuclear collisions of the bosonic ${}^{4}$He$^{*} +{}^{4}$He$^{*}$ and fermionic ${}^{3}$He$^{*} + {}^{3}$He$^{*}$ systems, and heteronuclear collisions of the mixed ${}^{3}$He$^{*} +{}^{4}$He$^{*}$ system, are investigated over a temperature range 1 $μ$K to 1 K. Carefully constructed Born-Oppenheimer molecular potentials are used to describe the electrostatic interaction between the colliding atoms, and complex optical potentials used to represent loss through ionization from the ${}^{1,3}Σ$ states. Magnetic spin-dipole mediated transitions from the ${}^{5}Σ$ state are included and results reported for spin-polarized and unpolarized systems. Comparisons are made with experimental results, previous semi-classical models, and a perturbed single channel model.