Quantum paramagnets on the honeycomb lattice and field-induced Néel order: Possible application to Bi$_3$Mn$_4$O$_{12}$(NO$_3$)

Motivated by recent experiments on the spin-3/2 frustrated bilayer honeycomb antiferromagnet Bi$_3$Mn$_4$O$_{12}$(NO$_3$), we study the spin-S Heisenberg model on the honeycomb lattice with various additional exchange interactions which frustrate Néel order. Using spin wave theory, exact diagonalization, and bond operator theory, we consider the effects of (i) second-neighbor exchange, (ii) biquadratic exchange for $S = 3/2$ which leads to an AKLT valence bond solid, and (iii) bilayer coupling which leads to an interlayer dimer solid. We show that the resulting paramagnetic states undergo a transition to Néel order beyond a critical magnetic field. We discuss experimental implications for Bi$_3$Mn$_4$O$_{12}$(NO$_3$).