Divergent effects of static disorder and hole doping in geometrically frustrated β-CaCr2O4
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/ Abstract
Abstract The gallium substituted and calcium deficient variants of geometrically frustrated β-CaCr 2 O 4 , β-CaCr 2–2 x Ga 2 x O 4 (0.02≤ x ≤0.25) and β-Ca 1− y Cr 2 O 4 (0.075≤ y ≤0.15), have been investigated by X-ray powder diffraction, magnetization and specific heat measurements. This allows for a direct comparison of the effects, in a geometrically frustrated magnet, of the static disorder that arises from non-magnetic substitution and the dynamic disorder that arises from hole doping. In both cases, disturbing the Cr 3+ lattice results in a reduction in the degree of magnetic frustration. On substitution of Ga, which introduces disorder without creating holes, a gradual release of spins from ordered antiferromagnetic states is observed. In contrast, in the calcium-deficient compounds the introduction of holes induces static ferrimagnetic ordering and much stronger perturbations of the β-CaCr 2 O 4 host.
Journal: Journal of Solid State Chemistry