Magnetic Structure and Interactions in the Quasi-1D Antiferromagnet CaV$_2$O$_4$
/ Authors
O. Pieper, B. Lake, A. Daoud-Aladine, M. Reehuis, K. Prokeš, B. Klemke, K. Kiefer, Jiaqiang Yan, A. Niazi, D. Johnston
and 1 more author
/ Abstract
CaV2O4 is a spin-1 antiferromagnet, where the magnetic vanadium ions have an orbital degree of freedom and are arranged on quasi-one-dimensional zig-zag chains. The first- and second-neighbor vanadium separations are approximately equal suggesting frustrated antiferromagnetic exchange interactions. High-temperature susceptibility and single-crystal neutron diffraction measurements are used to deduce the dominant exchange paths and orbital configurations. The results suggest that at high temperatures CaV2O4 behaves as a Haldane chain, but at low temperatures, it is a spin-1 ladder. These two magnetic structures are explained by different orbital configurations and show how orbital ordering can drive a system from one exotic spin Hamiltonian to another.
Journal: Physical Review B