The Arecibo Arp 220 Spectral Census I: Discovery of the Pre-Biotic Molecule Methanimine and New Cm-wavelength Transitions of Other Molecules

An on-going Arecibo line search between 1.1 and 10 GHz of the prototypical starburst/megamaser galaxy, Arp 220, has revealed a spectrum rich in molecular transitions. These include the ``pre-biotic'' molecules: methanimine (CH$_{2}$NH) in emission, three $v_{2}=1$ direct l-type absorption lines of HCN, and an absorption feature likely to be from either $^{18}$OH or formic acid (HCOOH). In addition, we report the detection of two, possibly three, transitions of $λ$4-cm excited OH not previously detected in Arp~220 which are seen in absorption, and a possible absorption feature from the 6.668-GHz line of methanol. This marks the first distant extragalactic detection of methanimine, a pre-biotic molecule. Also, if confirmed, the possible methanol absorption line presented here would represent the first extragalactic detection of methanol at a distance further than 10 Mpc. In addition, the strong, previously undetected, cm-wave HCN $v_{2}=1$ direct l-type lines will aid the study of dense molecular gas and active star-forming regions in this starburst galaxy.